双马来酰亚胺树脂体系的固化反应研究

利用ＤＳＣ及原位ＦＴＩＲ技术研究了双马来酰亚妥树脂体系的固化反应，获得了在固化反应过程中各组分的转化率与时间的关系，结合热分析数据，确立了最佳固化工艺。     

Synthetic resins: XV. Chelation ion exchange properties of 2,4- dinitrophenylhydrazone of resacetophenone-formaldehyde resin

A number of copolymers were synthesised by condensing the 2,4-dinitrophenylhydrazone of resacetophenone with substituted benzoic acids/ phenols and formaldehyde in the presence of sodium hydroxide or hydrochloric acid. The decomposition temperature, solubility and viscosity of the polymers have been determined. The ion-exchange properties have been studied by using a batch equilibrium method. The distribution of a number of metal ions between an aqueous solution and the resin have been measured. A wide range of pH and variable ionic strengths have been investigated.     

稀土树脂相分光光度法研究

在HCl—KCl(pH0.5)介质中,稀土—三溴偶氮胂二元络合物能较好地被阴离子交换树脂吸附。RE_2O_8在0～8μg/25ml范围内符合比尔定律,以双波长等吸收点法(测量波长λ_1=650nm,参比波长λ_2=740nm)扣除树脂背景影响,应用于稀土矿中稀土总量测定,结果令人满意。     

Microstructure-related fracture toughness and fatigue crack growth behaviour in toughened, anhydride-cured epoxy resins

Fracture toughness and fatigue crack propagation (FCP) of plain and modified anhydride-cured epoxy resin (EP) were studied at ambient temperature. Liquid carboxyl-terminated acrylonitrile-butadiene (CTBN) and silicon (SI) rubber dispersions were used as tougheners for the EP. The morphology of the modified EP was characterized by dynamic mechanical analysis (DMA) and by scanning electron microscopy (SEM). The fracture toughness, K_c, of the compositions decreased with increasing deformation rate. K_c of the EP was slightly improved by CTBN addition and practically unaffected by incorporation of the SI dispersion when tests were performed at low cross-head speed, v. Both modifiers improved K_c at high v, and also the resistance to FCP, by shifting the curves to higher stress intensity factor ranges, ΔK, by comparison with the plain EP. It was established that both fracture and fatigue performance rely on the compliance, J_R, at the rubbery plateau, and thus on the apparent molecular mass between crosslinks, M_c. The failure mechanisms were less dependent upon the loading mode (fracture, fatigue), but differed basically for the various modifiers. Rubber-induced cavitation and shear yielding of the EP were dominant for CTBN, whereas crack bifurcation and branching controlled the cracking in SI-modified EP. The simultaneous use of both modifiers resulted in a synergistic effect for both the fracture toughness at high deformation rate and the FCP behavior.     

低渗透油藏超短周期间歇注水方式研究

大港油田南区低渗透油藏两相共渗区窄，注水开发短期内含水上升迅速，根据间歇注水理论，并借鉴国内外油田的实验经验，1998年在舍女寺油田女20、女34区块开展超短周期（周期0．5－5d)间歇注水试验。总结不同注水周期和频率及油并不同含水级别对其效果的影响。认为超短周期间歇注水可改善油层动用状况，对中、低含水受益油井之注水井有较好的适用性，为低渗透油藏注水开发提出了一种经济有效的方法。图1参（王学立摘）。     

树脂热解炭制备碳化硅晶须

用自制的配合醛树脂热解和炭源，用ＳＩＯ２超细汾作原，根据碳热还原原理，利用常规加热和微波加热两种方式，分别制备了直径在纳米级的ＳｉＣ晶须，Ｘ射线衍射、透射电检测结果表明：制备工艺和条件对ＳｉＣ晶须的性质有较大的影响。     

水性木器涂料的研究进展

随着环境法规对涂料挥发性有机化合物(VOC)含量的限制,环境友好型水性涂料成为涂料工业的发展趋势。本文综述了水性木器涂料的研究进展。     

超Jaynes-Cummings模型中的原子置于热辐射场时的相干特性

超Jaynes一Cummings模型中的两能级原子置于热辐射场。通过求解原子与热辐射场相互作用过程中原子约化密度算符非对角元．精确得出子原子相干性的衰变规律。研究了在相互作用系统中外加驱动场时可保持原子的相干性，此时外加驱动场的时间演化与原子的跃迁频率、原子偶极矩、热库的温度和k模光子频率等因素有关。     

苯胺衍生物改性酚醛树脂的性能和结构表征

选用某种叔胺类化合物作苯酚和甲醛反应的催化剂,并加入少量苯胺衍生物,制备了一种分子量较高的改性酚醛树脂。根据IR、NMR和GPC的测试分析,对苯胺衍生物改性酚醛树脂的结构特征等进行了研究。它与环氧树脂合成压制的玻璃布层压板的浸水后绝缘电阻可达1011Ω以上,其它主要性能也达到了国外同类产品水平。     

己二酸二乙酯合成新工艺的研究

本文以离子交换树脂作为液固相酯化反应的催化剂 ,甲苯作为带水剂 ,合成己二酸二乙酯。应用本法 ,酯化反应产率高达 78%。同时对影响产率的诸因素进行了考察 ,其最佳反应条件为 :酸醇摩尔比 1∶4 ,催化剂用量为酸质量的 2 5 % ,反应时间为 10小时 ,反应温度 86～ 87℃ ,催化剂重复使用 4次 ,未出现活性明显下降 ,此工艺操作简单 ,反应条件温和 ,产率高 ,具有显著的工业应用价值。